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Thermal Vacuum Synthesis: Physical Processes in Nanomaterial Production

Received: 12 October 2024     Accepted: 4 November 2024     Published: 26 November 2024
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Abstract

The thermovacuum process offers an efficient and cost-effective method for producing nanomaterials by ensuring the continuous flow of dispersed material inside a spiral heating element. This is achieved by introducing the material into the heating element's cavity along with air, forming a two-phase gas-solid particle system. The material moves upward through the heated space, where pressure gradually decreases. Experimental studies on materials like carbon, brown coal, and zirconium dioxide indicate specific conditions are necessary for the system's continuous operation. One key requirement is that the mass of solid particles should not exceed 1.0 to 1.2 grams per liter of air entering the heating element. This limit ensures that nanodispersed and finely dispersed particles can move freely, avoiding collisions and allowing faster-moving particles to overtake slower ones. These particles increase in velocity and temperature as they pass through the heating element, with changes in heat capacity and particle motion contributing to wave motion and pulsed heat loads. The velocity at which the material particles travel depends on the thermal radiation from the heater walls and the energy generated by local pulse steam explosions, which create shock waves. Higher explosion energy results in increased particle velocity, greater impact angles against the heater walls, and higher environmental temperatures. These conditions lead to accelerated electron, proton, and other charged particle flows, forming plasma clots and neutrino clouds. The nanoparticles take various forms, including nanotubes, fullerenes, thin films, and crystals, reaching velocities up to a thousand kilometers per second and heating temperatures of up to 17 million degrees during pulses. This process consistently subjects the material to force, heat, deformation, and ionization, expediting the creation of nanodispersed materials with enhanced physicochemical and mechanical properties. The thermovacuum process not only improves the efficiency of thermotechnological equipment but also reduces energy consumption, production time, and costs. The research findings support its use in the continuous and effective production of high-quality nanomaterials.

Published in American Journal of Physics and Applications (Volume 12, Issue 4)
DOI 10.11648/j.ajpa.20241204.11
Page(s) 69-77
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Thermovacuum Process, Nanodispersed Materials, Spiral Heating Element, Gas-solid Particle System, Pulsed Steam Explosion, Shock Wave, Kinetic Energy, Nanotubes and Fullerenes

References
[1] S. D. Jadhav, I. A. Shaikh. Nanoparticles Synthesis Overview, Review Article. International Journal of Trend in Scientific Research and Development (IJTSRD), Issue: 3. Mar-Apr 2019. - pp. 426-428.
[2] B. A. Movchan. Electron Beam Technology of Evaporation and Vapor Deposition of Inorganic Materials with Amorphous, Nano- and Microstructure. Nanosystems, Nanomaterials, Nanotechnologies. - 2004. - V. 2, No. 4. – pp. 1103 –1126.
[3] V. P. Vinnikov, M. B. Generalov. Methods for Obtaining Nanodispersed Powders. Profession. 2016. - p. 240.
[4] T. E. Konstantinova, I. A. Danilenko, V. V. Tokiy, V. A. Glazunova. Obtaining Nanosized Powders of Zirconium Dioxide. From Novation to Innovation. Science and Innovation. 2005. V 1. No. 3. - pp. 76–87.
[5] V. Kutovyi. Physical Processes in the Thermal Vacuum System. American Journal of Physics and Applications. Vol. 10. No. 1. 2022. - pp. 1-7.
[6] Apparatus for Drying of Wet Dispersed Raw Materials. Kutovyi Volodymyr. Patent number W0/2007/013866 (A1). Claimed: 15.01.2005 Published: 02.01.2007. Application number WO2005UA00051 20051115. Priority document number: UA 200550007488 20050727.
[7] I. B. Zeldovich, Yu. P. Reisner. Physics Percussion Waves and High Temperature Hydrodynamic Phenomena. Science. 1966. - p. 686.
[8] I. A. Naumenko, I. G. Petrovsky. Shock Wave of Atomic Explosion. - M.: Military Publishing House. 1956. - p. 160.
[9] G. A. Mesyats, Y. I. Bichkov, V. V. Kremnev. Pulsed Nanosecond Electric Discharge in a Gas. – Achievements of Physical Sciences. 1972. Vol. 107. Issue. 6. – pp. 201-228.
[10] A. V. Zhukov, S. V. Chizhevskaya, Pio Piae, V. A. Panov. Hetero-phase Synthesis of Zirconium Hydroxide from Zirconium Oxychloride. Inorganic Materials. V. 55. No. 10. 2019. - pp. 1051-1058.
[11] V. O. Kutovyi, D. G. Malykhin, V. D. Virych, R. L. Vasilenko. Thermal-Vacuum Method for Obtaining Nanodispersed Zirconium Dioxide. East European Journal of Physics. No. 4. 2021. - pp. 86-90.
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  • APA Style

    Kutovyi, V. (2024). Thermal Vacuum Synthesis: Physical Processes in Nanomaterial Production. American Journal of Physics and Applications, 12(4), 69-77. https://doi.org/10.11648/j.ajpa.20241204.11

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    ACS Style

    Kutovyi, V. Thermal Vacuum Synthesis: Physical Processes in Nanomaterial Production. Am. J. Phys. Appl. 2024, 12(4), 69-77. doi: 10.11648/j.ajpa.20241204.11

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    AMA Style

    Kutovyi V. Thermal Vacuum Synthesis: Physical Processes in Nanomaterial Production. Am J Phys Appl. 2024;12(4):69-77. doi: 10.11648/j.ajpa.20241204.11

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  • @article{10.11648/j.ajpa.20241204.11,
      author = {Volodymyr Kutovyi},
      title = {Thermal Vacuum Synthesis: Physical Processes in Nanomaterial Production
    },
      journal = {American Journal of Physics and Applications},
      volume = {12},
      number = {4},
      pages = {69-77},
      doi = {10.11648/j.ajpa.20241204.11},
      url = {https://doi.org/10.11648/j.ajpa.20241204.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpa.20241204.11},
      abstract = {The thermovacuum process offers an efficient and cost-effective method for producing nanomaterials by ensuring the continuous flow of dispersed material inside a spiral heating element. This is achieved by introducing the material into the heating element's cavity along with air, forming a two-phase gas-solid particle system. The material moves upward through the heated space, where pressure gradually decreases. Experimental studies on materials like carbon, brown coal, and zirconium dioxide indicate specific conditions are necessary for the system's continuous operation. One key requirement is that the mass of solid particles should not exceed 1.0 to 1.2 grams per liter of air entering the heating element. This limit ensures that nanodispersed and finely dispersed particles can move freely, avoiding collisions and allowing faster-moving particles to overtake slower ones. These particles increase in velocity and temperature as they pass through the heating element, with changes in heat capacity and particle motion contributing to wave motion and pulsed heat loads. The velocity at which the material particles travel depends on the thermal radiation from the heater walls and the energy generated by local pulse steam explosions, which create shock waves. Higher explosion energy results in increased particle velocity, greater impact angles against the heater walls, and higher environmental temperatures. These conditions lead to accelerated electron, proton, and other charged particle flows, forming plasma clots and neutrino clouds. The nanoparticles take various forms, including nanotubes, fullerenes, thin films, and crystals, reaching velocities up to a thousand kilometers per second and heating temperatures of up to 17 million degrees during pulses. This process consistently subjects the material to force, heat, deformation, and ionization, expediting the creation of nanodispersed materials with enhanced physicochemical and mechanical properties. The thermovacuum process not only improves the efficiency of thermotechnological equipment but also reduces energy consumption, production time, and costs. The research findings support its use in the continuous and effective production of high-quality nanomaterials.
    },
     year = {2024}
    }
    

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    JO  - American Journal of Physics and Applications
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